Ex parte GULDI et al. - Page 4




          Appeal No. 1997-3360                                                        
          Application No. 08/119,785                                                  


          hydroxide” (Paper 23, examiner’s answer, page 4).                           
          Nevertheless, the examiner has taken the following position:                
                    Absent a showing of new or unobvious results, it                  
               would have been obvious to clean wafers by                             
               incorporating the step of washing the wafer in a                       
               warm ultrasonically agitated aqueous detergent                         
               solution of Cleveland to the dilute ammonium                           
               hydroxide cleaning solution of Basi ‘954 or Basi                       
               ‘457 because not only will this stabilize the                          
               properties of the semiconductor wafers as taught by                    
               Cleveland, but also because each step is known                         
               individually to improve the cleaning of wafers and                     
               the person of ordinary skill in the art would expect                   
               such combination to improve wafer cleaning in an                       
               additive or cumulative manner. [Examiner’s answer,                     
               p. 5.]                                                                 
          We disagree.                                                                
               Both Basi ‘954 and Basi ‘457 teach the use of dilute NH OH             
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          to remove heavy metal ion contamination that may be present on              
          the polished surface of a semiconductor material following an               
          oxidizing operation (column 2, lines 43-54 of Basi ‘954;                    
          column 2, lines 47-55 of Basi ‘457).  According to these prior              
          art references, the oxidizing operation removes metal oxide                 
          (e.g., silica) slurry particles, which are embedded in the                  
          surface of the semiconductor during the polishing operation                 
          and which evidently form siloxane-type bonds on the surface of              
          the semiconductor to render the surface to be hydrophobic                   

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