Ex Parte Ackerman et al - Page 2

                Appeal 2006-2179                                                                              
                Application 10/735,369                                                                        
                I.  APPEALED SUBJECT MATTER                                                                   
                      The subject matter on appeal is directed to providing a thermal barrier                 
                coating to an article, such as the components of a gas turbine engine.  See                   
                Specification at 1-2.  The method involves introducing “an effective surface-                 
                stabilization composition that inhibits sintering” of a primary ceramic                       
                coating defined by columnar grains on the components of the gas turbine                       
                engine.  Id.  The surface-stabilization composition comprises at least one                    
                Group 2 or 3 element of the Periodic Table, and at least one Group 5                          
                element of the Periodic Table, with the Group 5 element being present from                    
                practically near zero (e.g., 100 billion to 3 atomic ratio) to about 75% based                
                on atomic weight.  See, e.g., claims 1, 12, and 20.  Details of the appealed                  
                subject matter are recited in representative claims 1, 12 and 20 which are                    
                reproduced below:                                                                             
                      1.  A method for preparing a protected article, comprising the                          
                      steps of providing the article;                                                         
                      depositing a bond coat onto an exposed surface of the                                   
                      article; and                                                                            
                      producing a thermal barrier coating on an exposed surface                               
                      of the bond coat, wherein the step of producing the thermal                             
                      barrier coating includes the steps of                                                   
                      depositing a primary ceramic coating onto an exposed                                    
                      surface of the bond coat, and                                                           
                      depositing a stabilization composition onto an exposed                                  
                      surface of the primary ceramic coating, wherein the                                     
                      stabilization composition comprises a first element selected                            
                      from Group 2 or Group 3 of the periodic table, and a second                             
                      element selected from Group 5 of the periodic table, and                                
                      wherein the atomic ratio of the amount of the first element to                          
                      the amount of the second element is at least 1:3.                                       




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