Ex parte RADEMACHERS et al. - Page 9


                Appeal No. 1997-4318                                                                                                      
                Application 08/469,806                                                                                                    

                explain why one of ordinary skill in this art would have recognized that the range disclosed for the                      
                organic binders would apply to undisclosed inorganic binders.                                                             
                        The other applied references would have reasonably taught one of ordinary skill in this art to use                
                different amounts of sodium silicate as binders for, inter alia, cements, coating compositions, fertilizers,              
                detergents and clays.  The sole reference which discloses the use of sodium silicate with an inorganic                    
                pigment is 3M GB ‘259, wherein the reflective pigment particles, used in “liquid paint-like coating                       
                compositions,” 6 are “clusters or agglomerates in the range of at least 2 microns in diameter up to 70                    
                microns in diameter and consisting of an average size below 2 microns bound together by an inert                          
                transparent binder” and the “ordinary paint pigment of commerce” can be titanium dioxide that is                          
                “blended with sodium silicate solutions and atomized” in order to bond the particles together “in discrete                
                crush-resistant” manner (e.g., page 1, line 44, to page 2, line 15).  The pigment particles can be made                   
                weather resistant by treatment with an acid solution, and the resistance can be further increased by                      
                “firing at raised temperatures” (page 2, lines 15-21).  In the reference Example, “twenty parts by weight                 
                of standard titanium dioxide pigment . . . [is] mixed with 25 parts by weight of sodium silicate,” wherein                
                the “tiny spherical clusters of the original smaller titanium dioxide particles [are] bonded together with                
                sodium silicate,” the particles being further treated with aqueous ammonium chloride, dried and fired at                  
                elevated temperatures “to obtain a mass of clusters in the size range of 2 microns up to about 40                         
                microns” (page 2, lines 33-84).  It is further disclosed in 3M GB ‘259 that other pigments may be used,                   
                including red iron oxide (page 2, lines 76-84).  We find that the pigment particle size range disclosed in                
                this reference overlaps with the claimed particle size range in claims 13 and 26, and that the amount of                  
                binder suggested by the reference in the Example to be necessary in order that the particles are resistant                
                to crumbling, that is, crush-resistant when used in the paint-like compositions, is well above the claimed                
                weight percent range in these claims.                                                                                     
                        In Ferrigno, alkali metal silicates bind anhydrous mineral pigment particles together for calcining               
                (e.g., col. 4, lines 14-30).  Thus, this reference teaches that the binder is used in amounts of 1 to 10                  
                                                                                                                                          
                6  We find that 3M GB ‘259 (page 1, lines 20-29) cross references 3M GB ‘258 with respect to the                          
                use of “novel reflective pigment particles” in “liquid paint-like coating compositions,” the latter reference             
                (page 3, lines 37-79) in turn cross referencing the former.                                                               

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