Ex parte SHIBANUMA et al. - Page 3




          Appeal No. 1996-0684                                                        
          Application No. 08/116,550                                                  


          chromium oxide.  The examiner argues that it would have been                
          obvious to use that mixed catalyst in the gas-phase                         
          fluorination process disclosed by Manzer in column 6, EXAMPLES              
          4-5.  See the Examiner's Answer, paragraph bridging pages 3                 
          and 4.  We disagree.                                                        
               For the reasons succinctly set forth in the Appeal Brief,              
          pages 5 through 7, we find that the proposed combination of                 
          references is improper.  Manzer cites and discusses British                 
          Patent No. 2,030,981 (Ohsaka) in column 1, lines 19 through                 
          50.  There, Manzer suggests that the inorganic chromium (III)               
          catalysts of Ohsaka promote the oxidation of hydrogen chloride              
          to molecular chlorine and water and, therefore, cause a                     
          decrease in selective conversion from 1,1,1-                                
          trifluorochloroethane to 1,1,1,-2-tetrafluoroethane.  In                    
          contrast, Manzer discloses that "the catalyst of the present                
          invention," including the ruthenium catalyst exemplified in                 
          column 6, EXAMPLES 4-5, minimizes the oxidation of hydrogen                 
          chloride to molecular chlorine and water.  See Manzer, column               
          3, lines 5 through 43.  Manzer thus embarks on a different                  
          path, disclosing metal catalysts for use in the gas-phase                   
          fluorination of 1,1,1-trifluorochloroethane to 1,1,1,2-                     

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