LAGRANGE et al v. KONRAD et al - Page 86


                     Patent Interference No. 103,548                                                                                             

                          composition containing the salt in a medium appropriate for dyeing, the                                                
                          composition (B) being applied before or after the application of the                                                   
                          composition (B) being applied before or after the application of the                                                   
                          composition (A); and                                                                                                   
                     (vii) a quinone derivative comprising an ortho- or para-  benzoquinone, an                                                  
                          ortho- or para-benzoquinone monoimine or diimine, a 1,2- or1,4-                                                        
                          naphthoquinone, an ortho- or para-benzoquinone sulphonimide, ",T-                                                      
                          alkylenebis-1,4-benzoquinone or a 1,2- or 1,4-naphthoquinone monoimine or                                              
                          diimine, the 5,6-dihydroxyindoline of formula (I) and the quinone derivative                                           
                          being selected such that the difference in redox potential )E between the                                              
                          redox potential E1 of the 5,6-dihydroxyindoline of formula (I) determined at                                           
                          pH 7 in a phosphate medium on a vitreous carbon electrode by means of                                                  
                          voltammetry and the redox potential E.sub.q of the quinone derivative                                                  
                          determined at pH 7 in a phosphate medium by polarography on a mercury                                                  
                          electrode relative to the saturated calomel electrode such that:                                                       
                                      )E = Ei - Eq # 320 millivolts;                                                                             
                          the composition (B) being applied before or after the application of the                                               
                          composition (A).                                                                                                       
                     10.  A method according to claim 9, wherein composition (A) in                                                              
                     combination with iodide ions is applied to the keratinous fibres, the                                                       
                     application of the composition (A) being preceded or followed by the                                                        
                     application of the composition (B) which contains hydrogen peroxide in a medium                                             
                     appropriate for dyeing.                                                                                                     
                                                                                                                                                
                     11.  A method according to claim 9, wherein at least one composition (A)                                                    
                     in combination with hydrogen peroxide and having a pH of between 2 and 7 is                                                 
                     applied to the keratinous fibres, the application of the composition (A) being                                              
                     preceded or followed by the application of the composition (B) which contains                                               
                     iodide ions in a medium appropriate for dyeing.                                                                             
                                                                                                                                                
                     12.  A method according to claim 10, wherein the iodide ions are present                                                    
                     in the composition (A) or (B) in a proportion of between 0.007 and 4% by weight,                                            
                     expressed as I-ions, relative to the total weight of the                                                                    
                     composition (A) or (B).                                                                                                     
                                                                                                                                                
                     13.  A method according to claim 9, wherein composition (A) is applied to the                                               
                     keratinous fibres and an acid aqueous composition (B) is then applied, the                                                  
                     composition (A) or the composition (B) containing at least one nitrite comprising                                           
                     alkali metal nitrite, alkaline-earth metal nitrite or ammonium nitrite or the nitrite of                                    
                     any other cosmetically acceptable cation, an organic nitrite derivative or a nitrite                                        
                     vector generating a nitrite of the type define above.                                                                       
                     14.  A method according to claim 13, wherein the nitrite is present in a                                                    
                     proportion of between 0.02 and 1 mole/liter.                                                                                
                                                                                                                                                






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