RIGGINS et al v. HOLSTEN et al - Page 53



          Interference 103,685                                                          
               Date 2/20/90    Project No. Nomex Dyeing    Book No. 1664                
                         Evaluation of “Carrier” Candidates                             
               see p. 28 for procedure                                                  
                                    1              2               3                    
               Wt. Of fabric        10.83          10.64           11.53                
               diethylbenzamide     4gm                                                 
               Ninol 11-CM Coconut                 4gm                                  
               diethanolamide                                                           
               Ninol 201 Oleic                                                          
               diethanolamide                                      4gm                  
               Acid blue #62(2%owf)X               X               X                    
               % exhaust            90             10              10                   
               Fabric Color         80% full(not as deep as                             
                                         dibutylfomamide*                               
                                                   . . . .                              
                                                                   . . . .              
                                    11.56          10.53           11.45                
               * Color may be typical of soluble vs insoluble -                         
                    more penetration                                                    
               % Addn               6.7            -1.0            -1.0                 
               Boiling washes       11.23          10.62           11.53                
                    Diethylbenzamide is of particular interest in                       
               reference to the results of p. 28 this book in which                     
               dimethyl benzamide was relatively ineffective under                      
               these same conditions.  It is quite unlikely that the                    
               solvent properties of these two very similar compounds                   
               differ greatly - but it is very likely that solubility                   
               in water is much less for the diethyl than for the                       
               dimethyl.  This pair exhibits this effect, as does the                   
               methyl, ethyl and cyclohexylpyrrolidones and perhaps                     
               other compounds in this same family.  Other effects such                 
               as base strength or molecular size may affect dyeing                     
               efficiency on Nomex but it seems clear that solubility                   
               in water strongly influences efficiency within this                      
               family of dyeing aides.                                                  
               Howell Riggins 3/22/90         Penny E. Haith 5/4/90                     

                                         -53-                                           




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