Appeal No. 1998-1216 Application 08/356,194 deposition and without exposing the first film to air successively forming a second film by chemical vapor deposition on the first film, wherein the second film is a metal oxynitride and the metal of this compound constitutes the metal used to form the first film. Further details of this appealed subject matter are set forth in representative independent claim 8, which reads as follows: 8. A method of manufacturing a semiconductor device comprising the steps of providing a semiconductor substrate having a patterned insulating layer formed on a surface thereof, the insulating layer being patterned to form at least one contact hole defining side walls of said insulating layer and an exposed portion of the surface of said semiconductor substrate; forming a first film by a first chemical vapor deposition to cover the patterned insulating layer, the side walls and the exposed portion, the first film being a pure metal selected from a group consisting of titanium, tungsten, molybdenum, hafnium, and zirconium; without exposing the first film to air, successively forming a second film by a second chemical vapor deposition on the first film, said second film being a metal oxynitride and the metal of the compound being the metal used to form the first film; and then forming a tungsten film on the second film to fill each contact hole with the tungsten film, said first and second chemical vapor depositions being performed using a gas consisting of a halogen and said metal. 2Page: Previous 1 2 3 4 5 6 7 8 NextLast modified: November 3, 2007