Appeal No. 1997-3635 Application No. 08/498,357 metallization layer from oxidation. As disclosed on pages 8 and 9 of the specification, the surface of a barrier metallization layer is coated in-situ with a thin silicon layer prior to its removal from the reaction chamber. Additionally, the silicon layer may be sintered with the barrier layer to form a metal silicide which serves as a passivation layer as well as providing a low contact resistance to the underlying barrier layer. The disclosure on pages 16 through 18 teaches that any one of the Chemical Vapor Deposition (CVD) methods: Plasma Enhanced Chemical Vapor Deposition (PECVD) methods, and Physical Vapor Deposition (PVD) sputtering methods may be used for forming the barrier metallization and the silicon layers. Representative independent claim 1 is reproduced as follows: 1. A method for forming a barrier metallization layer upon a semiconductor substrate comprising: providing a semiconductor substrate; forming upon the semiconductor substrate a barrier metallization layer; and forming in-situ upon the barrier metallization layer a silicon layer, the silicon layer being formed without exposing the barrier metallization layer to oxygen, the silicon layer having a thickness such that the contact 2Page: Previous 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 NextLast modified: November 3, 2007