Appeal No. 1998-2916 Application No. 08/606,975 filled with an electrically conductive material after an adhesion layer, and a barrier layer in contact with the adhesion layer, are formed in the contact hole. The adhesion layer is formed by reducing, with H , a gas of a halogenated product of a group IVB 2 element, at a flow ratio of 0.4 or greater of group IVB element to H , in an ECR plasma CVD process. Appellant 2 asserts at page 4 of the specification that the selection of a flow ratio of 0.4 or greater of group IVB element to H in the 2 formation of the adhesion layer reduces grain growth of the group IVB metal, thereby improving the eventual performance of the conductive material. Representative claim 1 is reproduced as follows: 1. A method of producing a semiconductor device having a contact hole in a layer on a substrate of the device, comprising the steps of: forming an insulating layer on a semiconductor substrate; forming a contact hole in the insulating layer to expose a selected portion of the semiconductor 2Page: Previous 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 NextLast modified: November 3, 2007