Ex Parte SIMON et al - Page 4




                 Appeal No. 2001-1118                                                                                                               
                 Application 09/262,690                                                                                                             
                          but substantially all of the first layer deposited on the sidewalls of the via during the Rf                              
                          biased sputter deposition of the second layer is unaffected and wherein the second liner                                  
                          layer is also substantially removed from the bottom of the via during the sputter                                         
                          deposition.                                                                                                               
                          23.    A semiconductor article comprising:                                                                                
                          a.  a material having a via;                                                                                              
                          b.  a first layer deposited in the via, the first layer lining the via;                                                   
                          c.  a second liner layer deposited on the first liner layer, the second layer is deposited                                
                          using Rf biased sputter deposition; wherein the first layer deposited on the bottom of the                                
                          via is substantially removed during the Rf biased sputter deposition of the second layer                                  
                          but substantially all of the first layer deposited on the sidewalls of the via during the Rf                              
                          biased sputter deposition of the second layer is unaffected.                                                              
                          8.  The applicants’ specification defines “substantially removed” as follows:                                             
                          By “substantially removed” it is meant that the amount of first deposited material                                        
                          remaining on the bottom of the via, 100, after the sputter deposition is insufficient to                                  
                          significantly effect the electrical and capacitive potential of the final structure.                                      
                          (Application at 12, lines 1-5).                                                                                           
                                                          The Chakravorty reference                                                                 
                          9.  Chakravorty discloses an interconnect structure with a layer of tantalum metal and                                    
                 tantalum oxide in between the conductor and the insulator in the interconnect structure.  (Col. 3,                                 
                 lines 1-4).  The tantalum/tantalum oxide layer is patterned to expose the underlying electroplating                                
                 seed layers, while maintaining electrical contact between the electroplating seed layers and the                                   
                 edges of the substrate through the tantalum layer.  (Col. 3, lines 51-55).                                                         


                          Chakravorty explains that “[t]he underlying tantalum layer will ensure good electrical                                    
                 interconnection of all of the individual plating seed layers” (col. 6, lines 14-16) and that the                                   
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