Ex Parte Ackerman et al - Page 3

                Appeal 2006-2179                                                                              
                Application 10/735,369                                                                        
                      12.  A method for preparing a protected article, comprising the                         
                      steps of                                                                                
                      providing a nickel-base superalloy article that is a                                    
                      component of a gas turbine engine;                                                      
                      depositing a bond coat onto an exposed surface of the                                   
                      article; and                                                                            
                      producing a thermal barrier coating on an exposed surface                               
                      of the bond coat, wherein the step of producing the thermal                             
                      barrier coating includes the steps of                                                   
                           depositing a yttria-stabilized zirconia primary                                    
                           ceramic coating onto an exposed surface of the bond coat,                          
                           infiltrating a stabilization composition into an exposed                           
                           surface of the primary ceramic coating, wherein the                                
                           stabilization composition comprises a first element                                
                           selected from Group 2 or Group 3 of the periodic table,                            
                           and a second element selected from Group 5 of the                                  
                           periodic table, and wherein the atomic ratio of the amount                         
                           of the first element to  the amount of the second element is                       
                           at least 1:3.                                                                      
                      20.  A method for preparing a protected article, comprising the                         
                      steps of                                                                                
                      providing the article;                                                                  
                      depositing a bond coat onto an exposed surface of the                                   
                      article; and                                                                            
                      producing a thermal barrier coating on an exposed surface                               
                      of the bond coat, wherein the thermal barrier coating comprises                         
                      a primary ceramic coating on the exposed surface of the bond                            
                      coat, and                                                                               
                      a sintering-inhibitor region at a surface of the primary ceramic                        
                      coating, wherein the sintering-inhibitor region comprises a first                       
                      element selected from Group 2 or Group 3 of the periodic table,                         
                      and a second element selected from Group 5 of the periodic                              
                      table, and wherein the atomic ratio of the amount of the first                          
                      element to the amount of the second element is at least 1:3.                            




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