Ex parte AZUMA et al. - Page 9




          Appeal No. 1998-0129                                       Page 9           
          Application No. 08/438,062                                                  


               From our review of Koyama, we find that Koyama discloses               
          (32.1.1, col. 1) that                                                       
               With the recent increase in the integration                            
               density of DRAMs, a large charge storage density has                   
               been required, so several high dielectric constant                     
               materials, i.e., PZT[1,2], PLZT[3], BaTiO [4],                         
                                                        3                             
               SrTiO [5] and (Ba Sr )TiO  [6] have been proposed for3          x  1-x   3                                             
               DRAM capacitors.  A DRAM capacitor film needs a high                   
               dielectric constant and low leakage current and high                   
               reliability for voltage stress.  We chose (Ba Sr                       
                                                            x 1-                      
               )TiO  among them due to the following reasons; (1)                     
               x   3                                                                  
               The composition control is easy, so the electrical                     
               characteristics should be stable. (2) The phase is                     
               paraelectric over the device operating temperature                     
               range, so the film should have no fatigue problems.                    
               . . .                                                                  
               This paper describes the fabrication and electrical                    
          properties of the stacked capacitor realized by                             
          utilizing                                                                   
          a high-dielectric-constant material (Ba Sr )TiO  for the                    
                                                      05 05   3                       
          first time.  ([] original).                                                 

          We find that Koyama, having considered several high dielectric              
          materials including, inter alia, PZT, PLZT, and BST, chose BST              
          for the reasons quoted, supra.  From these teachings of                     
          Koyama, we are in agreement with the examiner (answer, page 7)              
          that Koyama would have suggested replacing the PZT or PLZT                  
          layer of Miller with BST to exhibit stable electrical                       
          characteristics and to avoid the problem of fatigue.                        









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